Designing higher surface area metal-organic frameworks: are triple bonds better than phenyls?
نویسندگان
چکیده
We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 134 24 شماره
صفحات -
تاریخ انتشار 2012